Ultrathin Nitrogen-Doped Carbon Coated with CoP for Efficient Hydrogen Evolution

作者: Fulin Yang , Yongting Chen , Gongzhen Cheng , Shengli Chen , Wei Luo

DOI: 10.1021/ACSCATAL.7B00587

关键词:

摘要: Searching for non-noble-metal-based electrocatalysts with high efficiency and durability toward the hydrogen evolution reaction (HER) is vitally necessary for the upcoming clean and renewable energy systems. Here we report the synthesis of CoP nanoparticles encapsulated in ultrathin nitrogen-doped porous carbon (CoP@ NC) through a metal–organic framework (MOF) route. This hybrid exhibits remarkable electrocatalytic activity toward the HER in both acidic and alkaline media, with good stability. Experiments and …

参考文章(64)
N. Pentland, J. O'M. Bockris, E. Sheldon, Hydrogen Evolution Reaction on Copper, Gold, Molybdenum, Palladium, Rhodium, and Iron Mechanism and Measurement Technique under High Purity Conditions Journal of The Electrochemical Society. ,vol. 104, pp. 182- 194 ,(1957) , 10.1149/1.2428530
M. S. Dresselhaus, I. L. Thomas, Alternative energy technologies Nature. ,vol. 414, pp. 332- 337 ,(2001) , 10.1038/35104599
Tzu-Hsiang Lu, Chih-Jung Chen, Mrinmoyee Basu, Chong-Geng Ma, Ru-Shi Liu, The CoTe2 nanostructure: an efficient and robust catalyst for hydrogen evolution Chemical Communications. ,vol. 51, pp. 17012- 17015 ,(2015) , 10.1039/C5CC06806A
Miao Xu, Lei Han, Yujie Han, You Yu, Junfeng Zhai, Shaojun Dong, Porous CoP concave polyhedron electrocatalysts synthesized from metal–organic frameworks with enhanced electrochemical properties for hydrogen evolution Journal of Materials Chemistry. ,vol. 3, pp. 21471- 21477 ,(2015) , 10.1039/C5TA05018A
Yang Yang, Zhengyan Lun, Guoliang Xia, Fangcai Zheng, Mengni He, Qianwang Chen, Non-precious alloy encapsulated in nitrogen-doped graphene layers derived from MOFs as an active and durable hydrogen evolution reaction catalyst Energy and Environmental Science. ,vol. 8, pp. 3563- 3571 ,(2015) , 10.1039/C5EE02460A
Peng Xiao, Wei Chen, Xin Wang, A Review of Phosphide-Based Materials for Electrocatalytic Hydrogen Evolution Advanced Energy Materials. ,vol. 5, pp. 1500985- ,(2015) , 10.1002/AENM.201500985
Yongye Liang, Yanguang Li, Hailiang Wang, Hongjie Dai, Strongly coupled inorganic/nanocarbon hybrid materials for advanced electrocatalysis. Journal of the American Chemical Society. ,vol. 135, pp. 2013- 2036 ,(2013) , 10.1021/JA3089923
Yan Jiao, Yao Zheng, Mietek Jaroniec, Shi Zhang Qiao, Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions Chemical Society Reviews. ,vol. 44, pp. 2060- 2086 ,(2015) , 10.1039/C4CS00470A
Bryan E. Barton, Thomas B. Rauchfuss, Hydride-containing models for the active site of the nickel-iron hydrogenases. Journal of the American Chemical Society. ,vol. 132, pp. 14877- 14885 ,(2010) , 10.1021/JA105312P