Temperature dependence of the damping constant and the relaxation time close to the tetragonal-cubic phase transition in SrZrO3

作者: H. Yurtseven , A. Kiraci

DOI: 10.1016/J.MOLSTRUC.2016.08.050

关键词:

摘要: Abstract The damping constant Γsp due to the pseudospin-phonon coupling is calculated as a function of temperature using coupled model and energy fluctuation close tetragonal-cubic transition (TC = 1443 K) in SrZrO3. Using observed Raman frequencies linewidth (FWHM) soft modes (Eg A1g) from literature, predictions both models studied, are examined for this crystalline system. Values activation U extracted also inverse relaxation time predicted phase studied Divergence behaviour experimentally when TC approached tetragonal cubic diverges crystal. It indicated that second order here,

参考文章(38)
Dominique de Ligny, Pascal Richet, High-temperature heat capacity and thermal expansion ofSrTiO3andSrZrO3perovskites Physical Review B. ,vol. 53, pp. 3013- 3022 ,(1996) , 10.1103/PHYSREVB.53.3013
R. Vali, Band structure and dielectric properties of orthorhombic SrZrO3 Solid State Communications. ,vol. 145, pp. 497- 501 ,(2008) , 10.1016/J.SSC.2007.12.009
I. Laulicht, N. Luknar, Internal-mode line-broadening by proton jumps in KH2PO4 Chemical Physics Letters. ,vol. 47, pp. 237- 240 ,(1977) , 10.1016/0009-2614(77)80008-0
Chunhong Tang, Xiaomei Lu, Fengzhen Huang, Mengqiu Cai, Xin Wu, Ruwen Pen, Jinsong Zhu, Joint experiment and theory to study the band structure of SrZrO3 in orthorhombic phase Solid State Communications. ,vol. 149, pp. 2250- 2253 ,(2009) , 10.1016/J.SSC.2009.08.041
Shinya Hasegawa, Takayuki Sugimoto, Takuya Hashimoto, Investigation of structural phase transition behavior of SrZrO3 by thermal analyses and high-temperature X-ray diffraction Solid State Ionics. ,vol. 181, pp. 1091- 1097 ,(2010) , 10.1016/J.SSI.2010.06.035
J.F. Scott, J.A. Sanjurjo, Scaling of diverging optical phonon linewidth in displacive ferroelectrics Solid State Communications. ,vol. 58, pp. 687- 692 ,(1986) , 10.1016/0038-1098(86)90502-8
K. Aizu, Phenomenological lattice-dynamical theory of ferroelasticity Journal of Physics and Chemistry of Solids. ,vol. 32, pp. 1959- 1969 ,(1971) , 10.1016/S0022-3697(71)80161-0
Brendan J. Kennedy, Christopher J. Howard, Bryan C. Chakoumakos, High-temperature phase transitions in SrZrO 3 Physical Review B. ,vol. 59, pp. 4023- 4027 ,(1999) , 10.1103/PHYSREVB.59.4023
M. A. Hossain, J. P. Srivastava, A. Sattar, P. K. Khulbe, H. D. Bist, A study of phase transitions in (NH4)3H(SO4)2 crystals through Raman scattering Physica Status Solidi (a). ,vol. 141, pp. 335- 344 ,(1994) , 10.1002/PSSA.2211410211
M. Yamaguchi, M. Watanabe, K. Inoue, Y. Akishige, T. Yagi, Light scattering study of the coupled soft-optic and acoustic mode in hexagonal barium titanate. Physical Review Letters. ,vol. 75, pp. 1399- 1402 ,(1995) , 10.1103/PHYSREVLETT.75.1399