Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations

作者: Vikram Bhat , Eric R. Welin , Xuelei Guo , Brian M. Stoltz

DOI: 10.1021/ACS.CHEMREV.6B00731

关键词:

摘要: Stereoconvergent catalysis is an important subset of asymmetric synthesis that encompasses stereoablative transformations, dynamic kinetic resolutions, and transformations. Initially, only enzymes were known to catalyze processes, but recently various synthetic catalysts have been developed. This Review summarizes major advances in nonenzymatic, transition-metal-promoted transformations reported between 2005 2015.

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