Diastereoselective heterogeneous bromination of stilbene in a porous metal-organic framework.
作者： Simon C. Jones , Christina A. Bauer
DOI: 10.1021/JA900893P
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摘要: Postsynthetic modification of a porous MOF, Zn4O(trans-4,4′-stilbene dicarboxylate)3, with Br2 results in diastereoselective bromination the stilbene units. This is heterogeneous process, stereocontrol originating rigidity coordinated ligand and nature which allows “solution-like” access to reactive sites. X-ray diffraction N2 sorption studies suggest that partial serves increase stability this interpenetrated MOF structure.
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