Part 10: chemically triggered alkoxyamine C–ON bond homolysis in ionic liquid solvents
作者： Gerard Audran , Matisse Batsiandzy Ibanou , Paul Brémond , Jean-Patrick Joly , Sylvain R. A. Marque
DOI: 10.1039/C5RA13899J
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摘要: The homolysis of the C–ON bond three alkoxyamines – non-activated alkoxyamine 1, its N-methylated version 2 and N-oxidated 3 is investigated in several ionic liquids. These were selected as their prone to sharp solvent effects. EPR studies on these four liquids (IL) afforded results that similar those previously published (Polymer. Chem., 2012, 3, 2901; J. Org. 77, 9634). Indeed, correlations between Reichardt polarity constants ENT log kd, based Kalmet–Abboud–Taft relationship did not change significantly when ILs implemented.
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