Hydrogen adsorption properties of activated carbons with modified surfaces
作者： H. Takagi , H. Hatori , Y. Yamada , S. Matsuo , M. Shiraishi
DOI: 10.1016/J.JALLCOM.2004.03.139
关键词:
摘要: Abstract The hydrogen adsorption isotherms of activated carbon fibers loaded with platinum (Pt-ACF) and palladium (Pd-ACF) were accurately measured at ambient temperature over the pressure range 0–3.5 MPa by using a high-pressure apparatus. amounts adsorbed on Pt-ACF Pd-ACF samples larger than amount unmodified ACF sample. Detailed measurement up to 0.1 MPa indicated that increase in was due chemisorption metal. properties oxidized (NH 4 )S 2 O 8 or reduced flow 1073 K evaluated 77 303 K 0–3.5 MPa. decreased oxidation increased reduction. This result is attributable change pore structure: is, oxygen functional groups introduced surface inhibited into micropore an optimum diameter.
elsevier.com
sci-hub.se 参考文章(22)
Hideshi Hattori, Tetsuya Shishido, Molecular hydrogen-originated protonic acid site as active site on solid acid catalyst Catalysis Surveys From Asia. ,vol. 1, pp. 205- 213 ,(1997) , 10.1023/A:1019081031021
C. Moreno-Castilla, F. Carrasco-Marín, A. Mueden, The creation of acid carbon surfaces by treatment with (NH4)2S2O8 Carbon. ,vol. 35, pp. 1619- 1626 ,(1997) , 10.1016/S0008-6223(97)00121-8
Qinyu Wang, J. Karl Johnson, MOLECULAR SIMULATION OF HYDROGEN ADSORPTION IN SINGLE-WALLED CARBON NANOTUBES AND IDEALIZED CARBON SLIT PORES Journal of Chemical Physics. ,vol. 110, pp. 577- 586 ,(1999) , 10.1063/1.478114
Angela Lueking, Ralph T Yang, Hydrogen Spillover from a Metal Oxide Catalyst onto Carbon Nanotubes—Implications for Hydrogen Storage Journal of Catalysis. ,vol. 206, pp. 165- 168 ,(2002) , 10.1006/JCAT.2001.3472
J FREEL, Chemisorption on supported platinum I. Evaluation of a pulse method Journal of Catalysis. ,vol. 25, pp. 139- 148 ,(1972) , 10.1016/0021-9517(72)90211-4
C. C. Ahn, Y. Ye, B. V. Ratnakumar, C. Witham, R. C. Bowman, B. Fultz, Hydrogen desorption and adsorption measurements on graphite nanofibers Applied Physics Letters. ,vol. 73, pp. 3378- 3380 ,(1998) , 10.1063/1.122755
Hui-Ming Cheng, Quan-Hong Yang, Chang Liu, Hydrogen storage in carbon nanotubes Carbon. ,vol. 39, pp. 1447- 1454 ,(2001) , 10.1016/S0008-6223(00)00306-7
Toshiro Kuji, Yoshihito Matsumura, Hirohisa Uchida, Tatsuhiko Aizawa, Hydrogen absorption of nanocrystalline palladium Journal of Alloys and Compounds. ,vol. 330, pp. 718- 722 ,(2002) , 10.1016/S0925-8388(01)01597-3
A.C. Dillon, M.J. Heben, Hydrogen storage using carbon adsorbents: past, present and future Applied Physics A. ,vol. 72, pp. 133- 142 ,(2001) , 10.1007/S003390100788
N Satoh, J.-i Hayashi, H Hattori, Kinetic study of hydrogen adsorption on sulfated zirconia-supported platinum Applied Catalysis A-general. ,vol. 202, pp. 207- 213 ,(2000) , 10.1016/S0926-860X(00)00527-5