Bismuth Doped PbO 2 Coatings: Morphology and Electrocatalytic Properties
作者： O. Shmychkova , T. Luk'yanenko , A. Velichenko
关键词:
摘要: Modified PbO2 anodes doped with bismuth were prepared by means of electrodeposition in methanesulfonate solutions. The influence ions on morphological and electrocatalytic properties obtained coatings was studied. Both XRD patterns SEM micrographs demonstrated that incorporation diminishes the size crystal particles. It is shown, oxygen overpotential micromodified electrodes sensibly higher than non-modified PbO2-electrode. According to results a hypothesis mechanism which include transfer an increased number radical intermediates Bi(III) produce sensible amount Bi(IV) Bi(V) can participate O2 evolution process proposed.
hrpub.org参考文章(49)
J Iniesta, J González-Garcı́a, E Expósito, V Montiel, A Aldaz, Influence of chloride ion on electrochemical degradation of phenol in alkaline medium using bismuth doped and pure PbO2 anodes. Water Research. ,vol. 35, pp. 3291- 3300 ,(2001) , 10.1016/S0043-1354(01)00043-4
MA Quiroz, S Reyna, CA Martinez-Huitle, Sergio Ferro, Achille De Battisti, None, Electrocatalytic oxidation of p-nitrophenol from aqueous solutions at Pb/PbO2 anodes Applied Catalysis B-environmental. ,vol. 59, pp. 259- 266 ,(2005) , 10.1016/J.APCATB.2005.02.009
Enrique Brillas, Rosa Maria Bastida, Elisabet Llosa, Juan Casado, Electrochemical Destruction of Aniline and 4‐Chloroaniline for Wastewater Treatment Using a Carbon‐PTFE O 2 ‐ Fed Cathode Journal of The Electrochemical Society. ,vol. 142, pp. 1733- 1741 ,(1995) , 10.1149/1.2044186
Yuan Liu, Huiling Liu, Jun Ma, Xi Wang, None, Comparison of degradation mechanism of electrochemical oxidation of di- and tri-nitrophenols on Bi-doped lead dioxide electrode: Effect of the molecular structure Applied Catalysis B-environmental. ,vol. 91, pp. 284- 299 ,(2009) , 10.1016/J.APCATB.2009.05.039
R. Amadelli, A. Maldotti, A. Molinari, F.I. Danilov, A.B. Velichenko, Influence of the electrode history and effects of the electrolyte composition and temperature on O2 evolution at β-PbO2 anodes in acid media Journal of Electroanalytical Chemistry. ,vol. 534, pp. 1- 12 ,(2002) , 10.1016/S0022-0728(02)01152-X
A. Oury, A. Kirchev, Y. Bultel, Potential Response of Lead Dioxide/Lead(II) Galvanostatic Cycling in Methanesulfonic Acid: A Morphologico-Kinetics Interpretation Journal of The Electrochemical Society. ,vol. 160, ,(2013) , 10.1149/2.025302JES
S. Rothenberg, D. J. Payne, A. Bourlange, R. G. Egdell, A study of the metal to nonmetal transition in Bi-doped β-PbO2 by high resolution x-ray photoemission Journal of Applied Physics. ,vol. 102, pp. 113717- ,(2007) , 10.1063/1.2821362
A.B. Velichenko, D.V. Girenko, S.V. Kovalyov, A.N. Gnatenko, R. Amadelli, F.I. Danilov, Lead dioxide electrodeposition and its application: influence of fluoride and iron ions Journal of Electroanalytical Chemistry. ,vol. 454, pp. 203- 208 ,(1998) , 10.1016/S0022-0728(98)00256-3
Hongyi Li, Yong Chen, Yaohui Zhang, Weiqing Han, Xiuyun Sun, Jiansheng Li, Lianjun Wang, Preparation of Ti/PbO2–Sn anodes for electrochemical degradation of phenol Journal of Electroanalytical Chemistry. ,vol. 689, pp. 193- 200 ,(2013) , 10.1016/J.JELECHEM.2012.11.035
In‐Hyeong Yeo, Dennis C. Johnson, Electrocatalysis of Anodic Oxygen‐Transfer Reactions Effect of Groups III A and VA Metal Oxides in Electrodeposited β‐Lead Dioxide Electrodes in Acidic Media Journal of The Electrochemical Society. ,vol. 134, pp. 1973- 1977 ,(1987) , 10.1149/1.2100799