Infrared spectra of some hexahalogeno complexes
作者： Jiro Hiraishi , Ichiro Nakagawa , Takehiko Shimanouchi
DOI: 10.1016/0371-1951(64)80081-3
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摘要: Abstract Infrared spectra of hexachloro complexes have been measured from 14 to 35 μ. A strong band observed in the range 350 ∼ 300 cm −1 was assigned triply degenerate stretching vibration, ν 3 . normal co-ordinate treatment has made for these complex ions on basis molecular force field adequate some hexafluorides. The nature metal-halogen co-ordination bonds discussed considering bond constants obtained. result is agreement with that pure quadrupole resonance study halogens.
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