Silver-mediated aminophosphinoylation of propargyl alcohols with aromatic amines and H-phosphine oxides leading to α-aminophosphine oxides
作者： Qiang Huang , Lei Zhu , Dong Yi , Xiaohui Zhao , Wei Wei
DOI: 10.1016/J.CCLET.2019.07.049
关键词:
摘要: Abstract A new silver mediated aminophosphinoylation of propargyl alcohols with aromatic amines and H-phosphine oxides for the construction α-aminophosphine has been developed. The C N P bond could be efficiently formed in one pot operation via sequential O cleavage propargylic alcohols. This present methodology, which not only provides a simple alternative strategy synthesis oxides, but also opens window reactions dealkynalation coupling.
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