Head to head polymers-38. An improved synthesis of head to head polystyrene

作者: Enikö Földes , Gyorgy Deak , Ferenc Tüdös , Otto Vogl

DOI: 10.1016/0014-3057(93)90100-T

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摘要: Abstract A greatly improved and very reliable synthesis of head to polystyrene (HHPS) was worked out. HHPS prepared in a sequence four steps starting with reductive photodimerization acetophenone. The resultant 2,3-diphenyl-2,3-butanediol dehydrated vacuum 2,3-diphenyl-1,3-butadiene, which polymerized 1,4-poly(2,3-diphenyl-1,3-butadiene) (PDPBD). PDPBD then hydrogenated (reduced) potassium ethanol HHPS.

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