Electrochemical studies of copper(II) complexes derived from bulky Schiff bases. The crystal structure of bis[N-(1- adamantyl)-salicylaldiminato]copper(II)
作者： Juan M. Fernández-g. , Elias Acevedo-Arauz , Raúl Cetina-Rosado , Rubén A. Toscano , Norma Macías-ruvalcaba
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摘要: Three Schiff base ligands and their corresponding copper(II) complexes have been prepared characterized. Elemental analyses, mass spectra, i.r., electronic μeff the X- ray crystal structure for one of complexes, as well elemental 1H n.m.r. spectra ligands, obtained. The X-ray study shows that geometry around metal atom is intermediate between square planar tetrahedral. Electrochemical studies on reveal a dependence CuII/CuI potentials extent distortion observed in solid state.
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