Kinetics and mechanism of the iron(III)-catalyzed autoxidation of sulfur(IV) oxides in aqueous solution. 1. Formation of transient iron(III)-sulfur(IV) complexes

作者： Jochen Kraft , Rudi Van Eldik

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摘要: Mono-, bis-, and tris(sulfito) complexes of Fe(III), produced during the reaction aquated Fe(III) S(IV) oxides, undergo two successive redox reactions produce Fe(II), SO 4 2− , S 2 O 6 . Spectrophotometric kinetic measurements as well ion chromotographic analyses products were performed

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Kinetics and mechanism of the iron(III)-catalyzed autoxidation of sulfur(IV) oxides in aqueous solution. 1. Formation of transient iron(III)-sulfur(IV) complexes

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Kinetics and mechanism of the iron(III)-catalyzed autoxidation of sulfur(IV) oxides in aqueous solution. 1. Formation of transient iron(III)-sulfur(IV) complexes

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