Theory of Ion Exchange for Polyelectrolytes Undergoing Electrolytic Transference

摘要: It has been observed experimentally that polymeric ions generally have associated with them a large number of small opposite charge. These smaller ions, which are considered bound to the capable exchanging free in solution. The rate this exchange can be determined by certain electrolytic transference experiments involving use radioactive tracers. theory such is worked out formulating and solving appropriate differential equations subject boundary conditions. then shown how results these studies used for evaluating ion constants.