The synthesis and chiral crystal structures of two enantiomers of a Ag helical coordination polymer based on argentophilicity
作者： Ting Zhang , Hua-Qi Huang , Xiao-Yue Cheng , Dong Guo , Hong-Xin Mei
DOI: 10.1039/C5CE01948F
关键词:
摘要: Achiral ligand- and Ag(I)-driven spontaneous resolution occurred simultaneously in the formation of two enantiomers 1P 1M [Ag2(5-nip)(mpyz)] (5-nip = 5-nitroisophthalic, mpyz 2,3,5,6-tetramethylpyrazine), whose absolute sense a helix made achiral components is induced by metal Ag(I) through argentophilic interactions.
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sci-hub.se 参考文章(47)
Jung Soo Seo, Dongmok Whang, Hyoyoung Lee, Sung Im Jun, Jinho Oh, Young Jin Jeon, Kimoon Kim, A homochiral metal-organic porous material for enantioselective separation and catalysis Nature. ,vol. 404, pp. 982- 986 ,(2000) , 10.1038/35010088
Jian Zhang, Shumei Chen, Areg Zingiryan, Xianhui Bu, Integrated Molecular Chirality, Absolute Helicity, and Intrinsic Chiral Topology in Three-Dimensional Open-Framework Materials Journal of the American Chemical Society. ,vol. 130, pp. 17246- 17247 ,(2008) , 10.1021/JA8075692
A. Corma, H. García, F. X. Llabrés i Xamena, Engineering Metal Organic Frameworks for Heterogeneous Catalysis Chemical Reviews. ,vol. 110, pp. 4606- 4655 ,(2010) , 10.1021/CR9003924
Hong-Xin Mei, Ting Zhang, Dan-Feng Wang, Rong-Bin Huang, Lan-Sun Zheng, A Zn-oxalate helix linked by a water helix: spontaneous chiral resolution of a Zn helical coordination polymer New Journal of Chemistry. ,vol. 39, pp. 2075- 2080 ,(2015) , 10.1039/C4NJ02017K
Stephen F. Mason, Origins of biomolecular handedness Nature. ,vol. 311, pp. 19- 23 ,(1984) , 10.1038/311019A0
Di Sun, Zhan-Hua Wei, Cheng-Feng Yang, Dan-Feng Wang, Na Zhang, Rong-Bin Huang, Lan-Sun Zheng, pH-Dependent Ag(I) coordination architectures constructed from 4-cyanopyridine and phthalic acid: from discrete structure to 2D sheet CrystEngComm. ,vol. 13, pp. 1591- 1601 ,(2011) , 10.1039/C0CE00539H
Matthew P. Lightfoot, Francis S. Mair, Robin G. Pritchard, John E. Warren, New Supramolecular packing motifs: pi-stacked rods encased in triply helical hydrogen bonded amide strands Chemical Communications. pp. 1945- 1946 ,(1999) , 10.1039/A905245C
Robert M. Hazen, David S. Sholl, Chiral selection on inorganic crystalline surfaces. Nature Materials. ,vol. 2, pp. 367- 374 ,(2003) , 10.1038/NMAT879
Cheng Wang, Teng Zhang, Wenbin Lin, Rational synthesis of noncentrosymmetric metal-organic frameworks for second-order nonlinear optics. Chemical Reviews. ,vol. 112, pp. 1084- 1104 ,(2012) , 10.1021/CR200252N
Jian Zhang, Shumei Chen, Tao Wu, Pingyun Feng, Xianhui Bu, Homochiral Crystallization of Microporous Framework Materials from Achiral Precursors by Chiral Catalysis Journal of the American Chemical Society. ,vol. 130, pp. 12882- 12883 ,(2008) , 10.1021/JA805272J