Catalysis of carbon monoxide oxidation by cerium dioxide I. Correlations between catalytic activity and electrical conductivity

作者: M BREYSSE

DOI: 10.1016/0021-9517(72)90268-0

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摘要: Abstract A mechanism involving the oxidation and reduction of solid is presented for carbon monoxide on cerium dioxide. Expressions reaction rate electrical conductivity catalyst are derived from this mechanism. Experiments have been performed in which these two quantities simultaneously recorded. The results agree with proposed

参考文章(6)
R. N. Blumenthal, P. W. Lee, R. J. Panlener, Studies of the Defect Structure of Nonstoichiometric Cerium Dioxide Journal of The Electrochemical Society. ,vol. 118, pp. 123- 129 ,(1971) , 10.1149/1.2407923
Günther Rienäcker, Margarete Birckenstaedt, Über die Beeinflussung oxydischer Katalysatoren durch Zuschläge II. Die katalytische Oxydation des Kohlenoxyds und des Wasserstoffs an Thoriumoxyd-Ceroxyd-Mischungen Zeitschrift für anorganische und allgemeine Chemie. ,vol. 262, pp. 81- 94 ,(1950) , 10.1002/ZAAC.19502620113
R.N. Blumenthal, R.J. Panlener, Electron mobility in nonstoichiometric cerium dioxide at high temperatures Journal of Physics and Chemistry of Solids. ,vol. 31, pp. 1190- 1192 ,(1970) , 10.1016/0022-3697(70)90329-X
G�nther Rien�cker, Y�O Wu, Eigenschaften von Cer/Lanthan‐Mischoxyden, insbesondere als Katalysatoren der Oxydation des Kohlenoxydes Zeitschrift für anorganische und allgemeine Chemie. ,vol. 315, pp. 121- 135 ,(1962) , 10.1002/ZAAC.19623150302
Bernard J. Wood, Henry Wise, Robert S. Yolles, Selectivity and stoichiometry of copper oxide in propylene oxidation Journal of Catalysis. ,vol. 15, pp. 355- 362 ,(1969) , 10.1016/0021-9517(69)90304-2