(+)‐(1R,2S,3R)‐Tetracarbonyl[(1–3η)‐1‐(Phenylsulfonyl)‐ But‐2‐en‐1‐yl]Iron(1+) Tetrafluoroborate

作者: D. Enders , B. Jandeleit , S. von Berg

DOI: 10.1002/0471264180.OS078.21

关键词:

摘要: (+)-(1R,2S,3R)-Tetracarbonyl[(1-3n)-1-(phenylsulfonyl)-but-2-en-1-yl]iron (1+)tetrafluoroborate R (−)-(E,S)-3-(benzyloxy)-1-butenyl phenyl sulfone I (+)-(E,1R,3S)-Tetracarbonyl[(3-(benzyloxy)-1-(phenylsulfonyl)-n2-but-1-ene]-iron (0) P (1+)tetrafluoroborate (1) Keywords: sulfur compounds; metalation reactions, iron; organometallic compounds, iron; carbon monoxide; sulfur compounds; ethers, miscellaneous; condensation, carbonyl-ylide condensation (Wittig-Horner-Emmons); addition, to CO; nonacarbonyldiiron; sulfur compounds; replacement miscellaneous; organometallic iron; fluoroboric acid: borate(1−), tetrafluoro-, hydrogen [16872-11-0]; impurities removal of paramagnetic impurities; as an allylic cation synthon

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