Transition Metal Complexes Containing Bidentate Phosphine Ligands
作者： W. Levason , C.A. Mcauliffe
DOI: 10.1016/S0065-2792(08)60007-2
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摘要: Publisher Summary This chapter describes several transition metal complexes containing bidentate phosphine ligands. The bonding in metal–phosphine ligands due to the formation of π-type bonds between and phosphorus atoms. Several techniques are used study complexes. These include mass spectroscopy infrared spectroscopy, nuclear magnetic resonance, electronic electron spin Mossbauer spectroscopy. A major complication diphosphine is relative complexity When a with ion, density on atom changes, ligand restricted conformation it can assume. Thus vibrational spectra free coordinated differ.
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