Selective adsorption of molybdenum(VI) from Mo–Re bearing effluent by chemically modified astringent persimmon

作者: Xiong Ying Xiong Ying , Wang HaiTao Wang HaiTao , Lou ZhenNing Lou ZhenNing , Shan WeiJun Shan WeiJun , Xing ZhiQiang Xing ZhiQiang

DOI: 10.1016/J.JHAZMAT.2010.12.077

关键词:

摘要: Astringent persimmon was chemically cross-linked by formaldehyde to obtain a novel kind of adsorption gel, which named as APF gel. The behaviors Mo(VI) and Re(VII) along with other coexisting metals onto the gel were studied in present paper. found be effective for while is almost completely inert toward rhenium calcium over whole hydrochloric acid concentration region. has low affinity iron, copper, lead, nickel, manganese zinc ions when HCl higher than 1 mol/L. exhibited selectivity only remarkably high capacity 1.05 mol/kg, behavior obeys Langmuir model. According thermodynamic kinetic studies, endothermic process followed pseudo-second order kinetics. Also, its excellent characteristics confirmed elution tests using column packed result provides new approach recovery from industrial waste effluent.

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