Gold Catalysis: Tandem Reactions of Diyne–Diols and External Nucleophiles as an Easy Access to Tricyclic Cage‐Like Structures

作者: A. Stephen K. Hashmi , Miriam Bührle , Michael Wölfle , Matthias Rudolph , Marcel Wieteck

DOI: 10.1002/CHEM.201001322

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摘要: Different diyne–diols composed of two terminal homopropargylic alcohol groups were prepared by bi‐directional synthesis. Subjection of the syn diastereomers to NAC–gold catalysts (…

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