Chromate reduction: reduction of potassium chromateby d-glucose and d-fructose to form Cr(III)-saccharide complexes
作者： Chebrolu Pulla Rao , Sharada Poornima Kaiwar
DOI: 10.1016/S0008-6215(92)84243-L
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摘要: Abstract The reduction of chromate by saccharides is paramount importance in the context chromiumtransport biological and ecological systems. Potassium has been shown to be reduced d -glucose D-fructose form Cr(III)-saccharide complexes via an intermediate Cr(V) species. These saccharide have isolated solid state for first time characterized analytical, spectroscopic, magnetic electrochemical methods. Bridged dinuclear Cr(III) proposed.
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