New ternary oxides of Re, Os, Ir and Pt with cubic crystal structures

作者: Arthur W. Sleight

DOI: 10.1016/0025-5408(74)90035-X

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摘要: Abstract A body-centered cubic structure related to the KSbO 3 strcture has been found for phases with compositions close Ba 0.5 IrO , Sr OsO and ReO . primitive also NaOsO BiPtO 3.5 BiOsO The ternary oxides Cd 2 Ir O 7 Ca 1.7 Os have prepared pyrochlore structure. All iridium contain 5+ are first oxide examples of in an oxidation state higher than four.

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