Synthesis of AlPO4 and kinetics of thermal decomposition of AlPO4·H2O-H4 precursor
作者： B. Boonchom , S. Youngme , T. Srithanratana , C. Danvirutai
DOI: 10.1007/S10973-007-8420-1
关键词:
摘要: The thermal decomposition of aluminum phosphate monohydrate AlPO4·H2O-H4 was investigated in air using TG-DTG/DTA. decomposes one step and final product (AlPO4) studied by X-ray powder diffraction, FTIR FT-Raman spectroscopy. activation energies dehydration reaction were calculated through the isoconversional methods Ozawa Kissinger-Akahira-Sunose (KAS), possible conversion functions have been estimated comparative methods. energy for different techniques found to be consistent. kinetic model that better described Fn as simple n-order corresponding function is f(α)=(1-α)2.75 g(α)=-[1-(1-a)-1.75/(1.75)].
springer.com
sci-hub.se 参考文章(24)
Sergey Vyazovkin, Computational aspects of kinetic analysis. Thermochimica Acta. ,vol. 355, pp. 155- 163 ,(2000) , 10.1016/S0040-6031(00)00445-7
Xiang Gao, David Dollimore, The thermal decomposition of oxalates: Part 26. A kinetic study of the thermal decomposition of manganese(II) oxalate dihydrate Thermochimica Acta. ,vol. 215, pp. 47- 63 ,(1993) , 10.1016/0040-6031(93)80081-K
V. Logvinenko, Solid State Coordination Chemistry. The quantitative thermoanalytical study of thermal dissociation reactions Journal of Thermal Analysis and Calorimetry. ,vol. 60, pp. 9- 15 ,(2000) , 10.1023/A:1010148028796
H. E. Kissinger, Reaction Kinetics in Differential Thermal Analysis Analytical Chemistry. ,vol. 29, pp. 1702- 1706 ,(1957) , 10.1021/AC60131A045
Jianhe Hong, Guanghui Guo, Keli Zhang, Kinetics and mechanism of non-isothermal dehydration of nickel acetate tetrahydrate in air Journal of Analytical and Applied Pyrolysis. ,vol. 77, pp. 111- 115 ,(2006) , 10.1016/J.JAAP.2006.02.007
Bernard Dennis Cullity, Elements of X-ray diffraction ,(1956)
Stephen T. Wilson, Brent M. Lok, Celeste A. Messina, Thomas R. Cannan, Edith M. Flanigen, Aluminophosphate molecular sieves: a new class of microporous crystalline inorganic solids Journal of the American Chemical Society. ,vol. 13, pp. 1146- 1147 ,(1982) , 10.1021/JA00368A062
Ray L Frost, Matt L Weier, Vibrational spectroscopy of natural augelite Journal of Molecular Structure. ,vol. 697, pp. 207- 211 ,(2004) , 10.1016/J.MOLSTRUC.2004.04.012
Kenneth J. Balkus, Laura J. Sottile, Scott J. Riley, Bruce E. Gnade, The preparation and characterization of AlPO4 thin films via laser ablation of AlPO4-H4 Thin Solid Films. ,vol. 260, pp. 4- 9 ,(1995) , 10.1016/0040-6090(95)09482-2
Sergey Vyazovkin, A unified approach to kinetic processing of nonisothermal data International Journal of Chemical Kinetics. ,vol. 28, pp. 95- 101 ,(1996) , 10.1002/(SICI)1097-4601(1996)28:2<95::AID-KIN4>3.0.CO;2-G