Rapid thermal plasma deposition of transparent nanocrystalline ZnO thin films and the effects of annealing

作者: Kwok Siong Teh , Joachim Pedersen , Heather Esposito

DOI: 10.1109/NEMS.2012.6196770

关键词:

摘要: Conductive, undoped zinc oxide nanocrystalline thin film with predominant c-axis orientation is prepared on crystalline and amorphous substrates using a rapid, one-step ambient-pressure, thermal plasma chemical vapor deposition process. Nonporous conformal films can be at temperature as low 160°C, an average grain size of 25 nm. Scanning electron micrographs indicate growth rate 15∼50 nm/min, depending factor including source temperature, pressure. X-ray diffraction shows (002) that independent the substrate's crystallinity. For thickness 200 nm, electrical conductivity ranges from 60–910 S/m. The results demonstrate potential CVD for rapid synthesis conductive ambient condition.

参考文章(13)
Shuzhi Li, Shengming Zhou, Hongxia Liu, Yin Hang, Changtai Xia, Jun Xu, Shulin Gu, Rong Zhang, Low-temperature hydrothermal growth of oriented [0001] ZnO film Materials Letters. ,vol. 61, pp. 30- 33 ,(2007) , 10.1016/J.MATLET.2006.03.145
S.J. Chen, Y.C. Liu, J.G. Ma, D.X. Zhao, Z.Z. Zhi, Y.M. Lu, J.Y. Zhang, D.Z. Shen, X.W. Fan, High-quality ZnO thin films prepared by two-step thermal oxidation of the metallic Zn Journal of Crystal Growth. ,vol. 240, pp. 467- 472 ,(2002) , 10.1016/S0022-0248(02)00925-9
Zheng Xu, Haiping He, Luwei Sun, Yizheng Jin, Binghui Zhao, Zhizhen Ye, Localized exciton emission from ZnO nanocrystalline films Journal of Applied Physics. ,vol. 107, pp. 053524- ,(2010) , 10.1063/1.3310804
Yang Zhang, Bixia Lin, Xiankai Sun, Zhuxi Fu, Temperature-dependent photoluminescence of nanocrystalline ZnO thin films grown on Si (100) substrates by the sol–gel process Applied Physics Letters. ,vol. 86, pp. 131910- ,(2005) , 10.1063/1.1891288
Masaya Shigeta, Anthony B Murphy, Thermal plasmas for nanofabrication Journal of Physics D. ,vol. 44, pp. 174025- ,(2011) , 10.1088/0022-3727/44/17/174025
Brian D. Sosnowchik, Liwei Lin, Rapid synthesis of carbon nanotubes via inductive heating Applied Physics Letters. ,vol. 89, pp. 193112- ,(2006) , 10.1063/1.2387942
Teresa M. Barnes, Jacquelyn Leaf, Cassandra Fry, Colin A. Wolden, Room temperature chemical vapor deposition of c-axis ZnO Journal of Crystal Growth. ,vol. 274, pp. 412- 417 ,(2005) , 10.1016/J.JCRYSGRO.2004.10.015
J. Y. Guo, F. Gitzhofer, M. I. Boulos, Induction plasma synthesis of ultrafine SiC powders from silicon and CH4 Journal of Materials Science. ,vol. 30, pp. 5589- 5599 ,(1995) , 10.1007/BF00356691
Lei Luo, Brian D. Sosnowchik, Liwei Lin, Room temperature fast synthesis of zinc oxide nanowires by inductive heating Applied Physics Letters. ,vol. 90, pp. 093101- ,(2007) , 10.1063/1.2709618