Radiative transition probabilities in the X2Πg state of CO2

摘要: Abstract Using ab initio calculated potential energy and electric dipole moment functions, absolute radiative transition probabilities between the rovibronic Renner–Teller states of electronic ground state X 2 Π g CO + have been evaluated. The eigenstates were obtained (up to 6500 cm - 1 J ⩽ 13 ) from variational calculations including spin–orbit angular momentum couplings. intensities for rovibrational neutral state, by a similar approach, are found be in excellent agreement with experimental data. For presented results expected accuracy. It is that overtone antisymmetric stretching mode magnitude as fundamental transitions, contrast . theoretically generated IR-emission spectrum compared limb Mars atmosphere, measured Thermal Emission Spectrometer on Global Surveyor.