Multi-layer membrane model for mass transport in a direct ethanol fuel cell using an alkaline anion exchange membrane

作者: Hafez Bahrami , Amir Faghri

DOI: 10.1016/J.JPOWSOUR.2012.06.057

关键词:

摘要: Abstract A one-dimensional, isothermal, single-phase model is presented to investigate the mass transport in a direct ethanol fuel cell incorporating an alkaline anion exchange membrane. The electrochemistry analytically solved and closed-form solution provided for two limiting cases assuming Tafel expressions both oxygen reduction oxidation. multi-layer membrane proposed properly account diffusive electroosmotic of through fundamental differences crossover positive negative drag coefficients are discussed. It found that significantly reduced upon using instead proton membrane, especially at current densities higher than 500 A m − 2 .

参考文章(43)
YS Li, TS Zhao, WW Yang, None, Measurements of water uptake and transport properties in anion-exchange membranes International Journal of Hydrogen Energy. ,vol. 35, pp. 5656- 5665 ,(2010) , 10.1016/J.IJHYDENE.2010.03.026
Xiaoming Ren, Thomas E. Springer, Thomas A. Zawodzinski, Shimshon Gottesfeld, Methanol transport through Nafion membranes : Electro-osmotic drag effects on potential step measurements Journal of The Electrochemical Society. ,vol. 147, pp. 466- 474 ,(2000) , 10.1149/1.1393219
Naoko Fujiwara, Zyun Siroma, Shin-ichi Yamazaki, Tsutomu Ioroi, Hiroshi Senoh, Kazuaki Yasuda, Direct ethanol fuel cells using an anion exchange membrane Journal of Power Sources. ,vol. 185, pp. 621- 626 ,(2008) , 10.1016/J.JPOWSOUR.2008.09.024
Z. H. Wang, C. Y. Wang, Mathematical Modeling of Liquid-Feed Direct Methanol Fuel Cells Journal of The Electrochemical Society. ,vol. 150, ,(2003) , 10.1149/1.1559061
Jeremy P. Meyers, John Newman, Simulation of the Direct Methanol Fuel Cell III. Design and Optimization Journal of The Electrochemical Society. ,vol. 149, ,(2002) , 10.1149/1.1473190
Michael J Moran, Howard N Shapiro, Daisie D Boettner, Margaret B Bailey, None, Fundamentals of Engineering Thermodynamics ,(1988)
Shuiyun Shen, T. S. Zhao, Jianbo Xu, Yinshi Li, High performance of a carbon supported ternary PdIrNi catalyst for ethanol electro-oxidation in anion-exchange membrane direct ethanol fuel cells Energy and Environmental Science. ,vol. 4, pp. 1428- 1433 ,(2011) , 10.1039/C0EE00579G