An X-ray structural study of nonvalence interactions and coordination in organometallic compounds. XXV. Crystal structures of 2′-nitrobenzenesulfonanilide and its N-phenylmercury derivative
作者： L. G. Kuz'mina , Yu. T. Struchkov , A. S. Peregudov , D. N. Kravtsov
DOI: 10.1007/BF00808558
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摘要: X-ray diffraction (~MoK~, 0/20 scan) has been used to determine the crystal structures of 2'-nitrobenzenesulfoanilide (I, R = 0.0425 from 2286 reflections) and its PhHg derivative (II, 0.0329 2069 reflections). The molecule compound Icontains an intramolecular hydrogen bond N-~...O medium strength involving 0 atom nitro-group (N...O 2.593(2) ~, angle N--H...O 139(2)~ which closes a planar six-membered ring. In II, as resul$ weak coordination Hg...O| (NO=) at distance 3.00(1) A, chelate ring is formed. Analysis details molecular geometry published data indicates that formed by H-bond in I greater than II.
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