One-Pot Synthesis of Organic-Sulfur-Zinc Hybrid Materials via Polycondensation of a Zinc Salt and Thiols Generated in Situ from Cyclic Dithiocarbonates.
作者： Bungo Ochiai , Hirohisa Konta
DOI: 10.3390/MOLECULES200815049
关键词:
摘要: Soluble organic-sulfur-zinc hybrid polymers were prepared via a one-pot reaction consisting of ring-opening addition and subsequent polycondensation. The first is the nucleophilic 2-ethylhexylamine to multifunctional cyclic dithiocarbonates giving multiple thiols in situ. sequential polycondensation situ generated with Zn(OAc)2 gave target polymers. This method enabled use shorter amine than previous purified thiols, which required octadecylamine obtain soluble product. obtained may be cast as composite films polystyrene poly(methyl methacrylate). Owing alkyl chain, calculated nD values products (1.60 or 1.61) are higher that product bearing octadecyl chains (1.53).
mdpi.com
core.ac.uk
sci-hub.se 参考文章(22)
Takeshi Moriguchi, Takeshi Endo, Polyaddition of Bifunctional Dithiocarbonates Derived from Epoxides and Carbon Disulfide. Synthesis of Novel Poly(thiourethanes) Macromolecules. ,vol. 28, pp. 5386- 5387 ,(1995) , 10.1021/MA00119A035
Young-Chul An, Nae-Youn Jang, Seung Woo Lee, Jung-Hyurk Lim, Kyung-Min Kim, Organic-Inorganic Polymer Hybrids of Polystyrene with Ladderlike Polyphenylsilsesquioxanes Polymer Journal. ,vol. 40, pp. 538- 542 ,(2008) , 10.1295/POLYMJ.PJ2008034
B OCHIAI, T ENDO, Carbon dioxide and carbon disulfide as resources for functional polymers Progress in Polymer Science. ,vol. 30, pp. 183- 215 ,(2005) , 10.1016/J.PROGPOLYMSCI.2005.01.005
Nobuhiro Kihara, Hidefumi Tochigi, Takeshi Endo, Synthesis and reaction of polymers bearing 5‐membered cyclic dithiocarbonate group Journal of Polymer Science Part A. ,vol. 33, pp. 1005- 1010 ,(1995) , 10.1002/POLA.1995.080330701
Akane Suzuki, Daisuke Nagai, Bungo Ochiai, Takeshi Endo, Facile synthesis and crosslinking reaction of trifunctional five‐membered cyclic carbonate and dithiocarbonate Journal of Polymer Science Part A. ,vol. 42, pp. 5983- 5989 ,(2004) , 10.1002/POLA.20436
Bungo Ochiai, Yuuki Kato, Takeshi Endo, One-Pot Synthesis of Graft Copolymer by Combination of Free Radical Polymerization and Polyaddition Macromolecules. ,vol. 42, pp. 8001- 8002 ,(2009) , 10.1021/MA901834D
G. S. Jha, G. Seshadri, A. Mohan, R. K. Khandal, Sulfur containing optical plastics and its ophthalmic lenses applications E-polymers. ,vol. 8, pp. 376- 402 ,(2008) , 10.1515/EPOLY.2008.8.1.376
Wonmun Choi, Michiko Nakajima, Fumio Sanda, Takeshi Endo, Novel one-pot polymer syntheses based on dithiols obtained from a five-membered cyclic dithiocarbonate and diamines Macromolecular Chemistry and Physics. ,vol. 199, pp. 1909- 1915 ,(1998) , 10.1002/(SICI)1521-3935(19980901)199:9<1909::AID-MACP1909>3.0.CO;2-L
R. Houbertz, L. Fröhlich, M. Popall, U. Streppel, P. Dannberg, A. Bräuer, J. Serbin, B.N. Chichkov, Inorganic–Organic Hybrid Polymers for Information Technology: from Planar Technology to 3D Nanostructures Advanced Engineering Materials. ,vol. 5, pp. 551- 555 ,(2003) , 10.1002/ADEM.200310096
Hiromichi TAKEBE, Ryota KITAGAWA, Daniel W. HEWAK, Non-toxic sulfide glasses and thin films for optical applications Journal of the Ceramic Society of Japan. ,vol. 113, pp. 37- 43 ,(2005) , 10.2109/JCERSJ.113.37