Magnesium octa(benzo-15-crown-5)phthalocyaninate in the sodium dodecyl sulfate solutions: A study using electron and 1H NMR spectroscopy
作者： N. F. Goldshleger , A. V. Chernyak , I. P. Kalashnikova , V. E. Baulin , A. Yu. Tsivadze
DOI: 10.1134/S1070363212050210
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摘要: The behavior of magnesium octa(benzo-15-crown-5)phthalocyaninate in water medium the presence sodium dodecyl sulfate was studied using both electronic and 1H NMR spectroscopy, including method two-dimensional 1H-1H correlation NOESY. In microheterogeneous environment CH3(CH2)11OSO3Na solutions at concentrations latter close to CMC phthalocyanine is monomeric form, while concentration less than critical micelle-formation it becomes a dimer or even more aggregated. results spectroscopic investigation indicate that preferrably binds micelle hydrophobic region latter.
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