New observation of near-reversible behaviors for the [Fe(CN)6]3-/4- redox couple in vesicular solution
作者： Yi Li , Jingcheng Hao , Sihui Zhan
DOI: 10.1016/J.JELECHEM.2009.04.012
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摘要: Abstract A typical salt-free zero-charged catanionic system was constructed by mixing C 14 H 29 N + ( CH 3 ) OH - (TTAOH) and lauric acid (LA). The electrochemical behaviors of K 4 [Fe(CN) 6 ] in TTAOH/LA micelle phase vesicle solutions at glassy carbon (GC) electrode different scan rate were obtained. pair well-defined redox peaks [ Fe CN / is observed vesicular solution with Δ E p = 61 mV the 0.001 V/s. Compared to electrochemistry aqueous micellar solution, reversibility significantly improved solution.
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