Cationic ring‐opening polymerization of monothiocarbonate with a norbornene group
作者： Nobukatsu Nemoto , Keiichiro Kakimoto , Takeshi Endo
DOI: 10.1002/POLA.10254
关键词:
摘要: This work deals with the cationic ring-opening polymerization of cyclic thiocarbonates a norbornene or norbornane moiety, that is, 5,5-(bicyclo[2.2.1]hept-2-ene-5,5-ylidene)-1,3-dioxane-2-thione (TC1) 5,5-(bicyclo[2.2.1]heptane-5,5-ylidene)-1,3-dioxane-2-thione (TC2), respectively. The reaction TC1 initiated by trifluoromethanesulfonic acid (TfOH), methyl trifluoromethanesulfonate (TfOMe), boron trifluoride etherate (BF3OEt2), triethyloxonium tetrafluoroborate (Et3OBF4) afforded unidentified products; however, underwent iodide as an initiator to afford polythiocarbonate because propagating end was stabilized covalent-bonding property. TC2 TfOH, TfOMe, BF3OEt2, Et3OBF4 good solubility in common organic solvents and narrow molecular weight distribution absence double-bond moiety. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Chem 40: 1698–1705,
harvard.edu
sci-hub.se 参考文章(7)
Fumio Sanda, Jun Kamatani, Takeshi Endo, The first anionic ring-opening polymerization of cyclic monothiocarbonate via selective ring-opening with C-S bond cleavage Macromolecules. ,vol. 32, pp. 5715- 5717 ,(1999) , 10.1021/MA9905472
Nobukatsu Nemoto, Fumio Sanda, Takeshi Endo, Controlled Cationic Ring-Opening Polymerization of Monothiocarbonate Macromolecules. ,vol. 33, pp. 7229- 7231 ,(2000) , 10.1021/MA000760U
Toshiro Ariga, Toshikazu Takata, Takeshi Endo, Cationic Ring-Opening Polymerization of Cyclic Carbonates with Alkyl Halides To Yield Polycarbonate without the Ether Unit by Suppression of Elimination of Carbon Dioxide1 Macromolecules. ,vol. 30, pp. 737- 744 ,(1997) , 10.1021/MA9607325
Toshikazu Takata, Takeshi Endo, Recent advances in the development of expanding monomers: Synthesis, polymerization and volume change Progress in Polymer Science. ,vol. 18, pp. 839- 870 ,(1993) , 10.1016/0079-6700(93)90019-9
Mitsumoto Murayama, Fumio Sanda, Takeshi Endo, Anionic Ring-Opening Polymerization of a Cyclic Carbonate Having a Norbornene Structure with Amine Initiators Macromolecules. ,vol. 31, pp. 919- 923 ,(1998) , 10.1021/MA970878J
Toshikazu Takata, Fumio Sanda, Toshiro Ariga, Hideo Nemoto, Takeshi Endo, Cyclic carbonates, novel expandable monomers on polymerization Macromolecular Rapid Communications. ,vol. 18, pp. 461- 469 ,(1997) , 10.1002/MARC.1997.030180602
Toshikazu Takata, Katsuhiro Amachi, Katsunori Kitazawa, Takeshi Endo, Unusual ring-opening polymerization of spiro orthocarbonate containing norbornene moiety Macromolecules. ,vol. 22, pp. 3188- 3190 ,(1989) , 10.1021/MA00197A053