Dibenzotetrathiafulvalene with Amino Groups: New Electron-Donor Molecule with Hydrogen-Bonding Functionalities
作者： Yasushi Morita , Eigo Miyazaki , Kozo Fukui , Suguru Maki , Kazuhiro Nakasuji
DOI: 10.1016/J.SYNTHMET.2005.07.161
关键词:
摘要: Abstract Dibenzotetrathiafulvalene (DBTTF) with two amino groups, DADBTTF, has been designed as a new TTF derivative intermolecular hydrogen-bonding functionalities and synthesized stable solid in air. The first oxidation potential of DADBTTF was negatively shifted by 0.24 V compared that DBTTF, suggesting noticeable change the electronic structure induced substitution effect groups. crystal shows E -type configuration this molecule columnar stacking through π…π interaction interplanar distance 3.5 A.
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