Cadmium-113 Nuclear Magnetic Resonance Spectroscopy in Bioinorganic Chemistry. A Representative Spin 1/2 Metal Nuclide
作者： Paul D. Ellis
DOI: 10.1007/978-94-009-7130-1_22
关键词:
摘要: The main theme of this chapter involves the utilization 113Cd NMR spectroscopy to probe interesting structural and dynamic problems in inorganic bioinorganic chemistry. Within first portion we have summarized most known chemical shifts coupling constants. Further, also presented introductory comments with regard relaxation mechanisms importance dynamics. Subsequently, discuss detail consequences that dynamics upon interpretation parameters shifts. discussion then solid state methods. Our recent work on cadmium-substituted porphyrins single crystals serve as examples. Finally, bring all these points into focus when examine cadmium a surrogate for Ca+2 Zn+2 systems. Here, limited our Concanavalin A skeletal Troponin C.
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Sture Forsén, Eva Thulin, Torbjörn Drakenberg, Joachim Krebs, Kenneth Seamon, A 113Cd NMR study of calmodulin and its interaction with calcium, magnesium and trifluoperazine FEBS Letters. ,vol. 117, pp. 189- 194 ,(1980) , 10.1016/0014-5793(80)80942-2
Hartwig Müller, Lutz Rösch, Darstellung und spektroskopische untersuchung von bis(tri-t-butylsilyl)quecksilber Journal of Organometallic Chemistry. ,vol. 133, pp. 1- 6 ,(1977) , 10.1016/S0022-328X(00)98111-7
K. T. Suzuki, T. Maitani, Cadmium-113 FT NMR-spectra of rabbit liver metallothioneins. Cellular and Molecular Life Sciences. ,vol. 34, pp. 1449- 1450 ,(1978) , 10.1007/BF01932344
James D. Otvos, Ian M. Armitage, Cadmium-113 NMR of metallothionein: direct evidence for the existence of polynuclear metal binding sites Journal of the American Chemical Society. ,vol. 101, pp. 7734- 7736 ,(1979) , 10.1021/JA00520A028
P. DuBois Murphy, B. C. Gerstein, Principal components of the cadmium-113 shielding tensors in cadmium sulfate hydrates: nuclear magnetic resonance study of cadmium coordinated with oxygen Journal of the American Chemical Society. ,vol. 12, pp. 3282- 3286 ,(1981) , 10.1021/JA00402A008
Paul D. Ellis, Ruth R. Inners, Hans J. Jakobsen, Cadmium-113 nuclear magnetic resonance spectroscopy. A probe for molecular structure and anisotropic motion in cadmium-substituted porphyrins The Journal of Physical Chemistry. ,vol. 86, pp. 1506- 1508 ,(1982) , 10.1021/J100206A009
M. Karplus, J. A. Pople, Theory of Carbon NMR Chemical Shifts in Conjugated Molecules The Journal of Chemical Physics. ,vol. 38, pp. 2803- 2807 ,(1963) , 10.1063/1.1733605
Kenneth L. Henold, Jamshid Soulati, John P. Oliver, Alkyl exchange reactions involving organometallic derivatives of groups II and III Journal of the American Chemical Society. ,vol. 91, pp. 3171- 3174 ,(1969) , 10.1021/JA01040A012
John W. Macklin, Robert A. Plane, Raman study of stepwise formation of bromide complexes of zinc, cadmium, and mercury in aqueous solution Inorganic Chemistry. ,vol. 9, pp. 821- 827 ,(1970) , 10.1021/IC50086A026
Marilyn J. Bain Ackerman, Joseph J. H. Ackerman, Cadmium-113 NMR of supercooled aqueous solutions The Journal of Physical Chemistry. ,vol. 84, pp. 3151- 3153 ,(1980) , 10.1021/J100461A003