Conductivities in Thionyl Chloride

作者: Mark Salomon

DOI: 10.1149/1.2127397

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摘要: Abstract : Conductivity measurements in thionyl chloride are reported for dilute solutions of AlCl3, LiAlCl4, and the tetrapropylammonium (Pr4N) salts Pr4NCl, Pr4NClO4, Pr4NAlCl4. The data electrolyte having concentrations range approximately 0.01 to 1 x 10 (expn -5) mole dm -3) were fitted empirically an equation Fuoss-Hsia type. In all cases except AlCl3 ion pair formation was found be extensive. appear complex possibly owing species such as Al2Cl6 Al2Cl7(-). effect ionic strength on solubility LiCl is discussed.

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