Glycidyl 4‐Functionalized‐1,2,3‐Triazole Polymers
作者： Dian Liu , Yijun Zheng , Werner Steffen , Manfred Wagner , Hans-Jürgen Butt
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摘要: A series of novel polymers, glycidyl 4-functionalized 1,2,3-triazole polymers (functionalized GTP) were synthesized by click functionalization azide polymer (GAP). Quantitative the side groups was achieved due to high reactivity azide–alkyne Huisgen cycloaddition under mild conditions. The characterized 1H NMR, 13C IR, GPC, DLS, DSC, and TGA. We confirmed that solubility, glass transition temperature, decomposition temperature controllable changing functional group attached at 4-position group. Functionalized GTP expands not only application field GAP toward non-explosive materials, but also variety poly(ethylene glycol) derivatives with different groups.
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