Production of 2,2,2-trifluoroacetyl chloride

作者: Albert L Dittman

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摘要: The process for the production of trifluoroacetyl chloride which comprises reacting 1,1-dichloro-2,2,2-trifluoroethane containing less than about 0.1% water by weight with oxygen in gas phase at a temperature up to 250*C presence ultraviolet radiation. Desirably reaction is conducted continuously an average residence time 0.1 1 hour.

参考文章(2)
John D Calfee, Jr Thomas A Wallace, Process for preparing trichloroacetyl chloride ,(1951)
Braid Milton, Lawlor Francis, Synthesis of fluorine compounds ,(1957)