The thermolysis of poly(methyl methacrylate) in the presence of phenyltin chlorides PhxSnCl4−x (x = 1–3)

作者: Jayakody A. Chandrasiri , Charles A. Wilkie

DOI: 10.1016/0141-3910(94)90181-3

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摘要: Abstract The thermal degradation of poly(methyl methacrylate) in the presence three phenyltin chlorides, PhSnCl 3 , Ph 2 SnCl and SnCl, has been studied a complete mechanistic interpretation reaction is provided. Only little monomeric methyl methacrylate produced significant amount starting polymer converted to non-volatile, cross-linked tin ester.

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