Chapter Three – Synthesis and Applications in Catalysis of Metal Complexes with Chelating Phosphinosulfonate Ligands
作者： Fan Jiang , Mathieu Achard , Christian Bruneau
DOI: 10.1016/B978-0-12-800976-5.00003-5
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摘要: Preparations of various types chelating sulfonates preligands are reported. They include achiral and optically active phosphinosulfonate imidazolium sulfonate zwitterionic species. Their coordination to transition metals forming the corresponding chelate complexes with palladium, nickel, platinum, rhodium, iridium, ruthenium is described. Applications well-defined ruthenium, as well in situ-generated copper derivatives homogeneous catalysis for fine chemistry polymerization complete this chapter.
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