Reactions of Cl2P3/2: Absolute rate constants for reaction with H2, CH4, C2H6, CH2Cl2, C2Cl4, and cC6H12
作者： D. D. Davis , W. Braun , A. M. Bass
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摘要: The absolute rate constants have been measured for several gas-phase chlorine atom-molecule reactions at 25°C by resonance fluorescence. These and their corresponding in units of cm3 mole−1 sec−1 are: The effects varying the substrate pressure, total light intensity chlorine-atom source on value bimolecular investigated all these reactions. Conditions under which no competing side reaction occurs were established reported conditions. For (2), (5), (6), (7), 8, there is a discrepancy factor two between this work values literature; it suggested that due to an error previously k/k upon relative measurements literature ultimately depend.
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