Fabrication of single-walled carbon nanotube/tin nanoparticle composites by electrochemical reduction combined with vacuum filtration and hybrid co-filtration for high-performance lithium battery electrodes

作者: Jae Hyun Lee , Byung-Seon Kong , Seung Bo Yang , Hee-Tae Jung

DOI: 10.1016/J.JPOWSOUR.2009.04.045

关键词:

摘要: Abstract Hybrids consisting of single-walled carbon nanotubes (SWNTs) and tin nanoparticles are prepared on substrates as anode materials for lithium-ion batteries via two different techniques: (i) hybrid co-filtration by simultaneous vacuum filtration SWNT/tin nanoparticle solutions (ii) a combined technique comprised electrochemical reduction. The resulting composites uniform thickness consist homogeneous dispersion in SWNT network. In the films, SWNTs close contact with each other substrate. films exhibit extended cycle life (capacity retention 80% at 50th cycle), high power characteristics up to 1.75 mA cm −2 , electrode density 5 mg cm enhanced reversible capacities (535 mAh g −1 composite cycle) because aggregation is prevented.

参考文章(30)
Thaddeus B Massalski, Hiroaki Okamoto, PRnbsp Subramanian, Linda Kacprzak, William W Scott, None, Binary alloy phase diagrams ASM International. ,vol. 3, pp. 2874- ,(1986)
Guangli Che, Brinda B. Lakshmi, Ellen R. Fisher, Charles R. Martin, Carbon nanotubule membranes for electrochemical energy storage and production Nature. ,vol. 393, pp. 346- 349 ,(1998) , 10.1038/30694
J.-M. Tarascon, M. Armand, Issues and challenges facing rechargeable lithium batteries Nature. ,vol. 414, pp. 359- 367 ,(2001) , 10.1038/35104644
T. Prem Kumar, R. Ramesh, Y.Y. Lin, George Ting-Kuo Fey, Tin-filled carbon nanotubes as insertion anode materials for lithium-ion batteries Electrochemistry Communications. ,vol. 6, pp. 520- 525 ,(2004) , 10.1016/J.ELECOM.2004.03.009
N. P. Armitage, J.-C. P. Gabriel, G. Grüner, Quasi-Langmuir–Blodgett thin film deposition of carbon nanotubes Journal of Applied Physics. ,vol. 95, pp. 3228- 3230 ,(2004) , 10.1063/1.1646450
Thomas M. Day, Patrick R. Unwin, Neil R. Wilson, Julie V. Macpherson, Electrochemical Templating of Metal Nanoparticles and Nanowires on Single-Walled Carbon Nanotube Networks Journal of the American Chemical Society. ,vol. 127, pp. 10639- 10647 ,(2005) , 10.1021/JA051320R
Min-Sik Park, Scott A. Needham, Guo-Xiu Wang, Yong-Mook Kang, Jin-Soo Park, Shi-Xue Dou, Hua-Kun Liu, Nanostructured SnSb/Carbon Nanotube Composites Synthesized by Reductive Precipitation for Lithium-Ion Batteries Chemistry of Materials. ,vol. 19, pp. 2406- 2410 ,(2007) , 10.1021/CM0701761
L. Simonin, U. Lafont, E.M. Kelder, SnSb micron-sized particles for Li-ion batteries Journal of Power Sources. ,vol. 180, pp. 859- 863 ,(2008) , 10.1016/J.JPOWSOUR.2008.03.014