摘要: Abstract The interactions between glass and water are many-sided the results of such depend on many parameters. It is well known that stability in depends composition glass. Amongst further parameters temperature plays a specific role because primarily determines whether interaction takes place with vapour or liquid water. In general durability very high. good condition surface ancient glasses, exposed to for long time, proves this impressively. However, impression usually does not show complicated occur yielding remarkable change structure microstructure surfaces. These phenomena shall be discussed detail. influenced by compounds dissolved This must taken into consideration especially when judging long-term behaviour limited aqueous volume. problem important some practical cases. was found corrosion continues even after components have reached their saturation, however, lower rate. Two examples discussed, HLW-containing stock fibers human tissues.
harvard.edu
elsevier.com
sci-hub.se 参考文章(10)
J. W. Shade, D. M. Strachan, Effect of high surface area to solution volume ratios on waste glass leaching American Ceramic Society Bulletin. ,vol. 65, pp. 1568- 1573 ,(1986)
H. Scholze, Chemical durability of glasses Journal of Non-crystalline Solids. ,vol. 52, pp. 91- 103 ,(1982) , 10.1016/0022-3093(82)90283-6
C. Maurer, D.E. Clark, L.L. Hench, B. Grambow, Solubility effects on the corrosion of nuclear defense waste glasses Nuclear and Chemical Waste Management. ,vol. 5, pp. 193- 201 ,(1985) , 10.1016/0191-815X(85)90078-6
AN IN VITRO STUDY OF THE CHEMICAL DURABILITY OF SILICEOUS FIBRES Annals of Occupational Hygiene. ,vol. 31, pp. 683- 692 ,(1987) , 10.1093/ANNHYG/31.4B.683
L.R. Pederson, D.R. Baer, G.L. McVay, M.H. Engelhard, Reaction of soda lime silicate glass in isotopically labelled water Journal of Non-crystalline Solids. ,vol. 86, pp. 369- 380 ,(1986) , 10.1016/0022-3093(86)90025-6
R. H. Do Remus, Y. Mehrotra, W. A. Lanford, C. Burman, Reaction of water with glass: influence of a transformed surface layer Journal of Materials Science. ,vol. 18, pp. 612- 622 ,(1983) , 10.1007/BF00560651
D. R. Baer, L. R. Pederson, G. L. McVay, Glass reactivity in aqueous solutions Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films. ,vol. 2, pp. 738- 743 ,(1984) , 10.1116/1.572561
R. G. Newton, The durability of glass: a review Glass Technology. ,vol. 26, pp. 21- 38 ,(1985)
G. Borchardt, G. H. Frischat, T. Richter, S. Scherrer, Short time leaching of a soda-lime glass in H2O and D2O Physics and Chemistry of Glasses. ,vol. 26, pp. 208- 212 ,(1985)
L. R. Pederson, COMPARISON OF SODIUM LEACHING RATES FROM A Na//2O. 3SiO//2 GLASS IN H//2O AND D//2O. Physics and Chemistry of Glasses. ,vol. 28, pp. 17- 21 ,(1987)