Catalytic oxidation of methanol to methyl formate over silver – a new purpose of a traditional catalysis system

作者: Zhi Yang , Jing Li , Xiangguang Yang , Yue Wu

DOI: 10.1007/S10562-004-3457-2

关键词:

摘要: Catalytic reaction was performed in the unregarded temperature region over silver catalysts with long catalytic lifetime for conversion of methanol to methyl formate. Oα-saturated or Oγ-saturated were studied individually identify roles Oα, Oγ oxidative esterification an unsupported polycrystalline catalyst. A synergic process is proposed based on coexistence α-oxygen species and γ-oxygen surface at about 573 K.

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