Isomorphous Lanthanide Complexes of a Tripodal N4O3 Ligand

作者: Paul V. Bernhardt , Bernadine M. Flanagan , Mark J. Riley

DOI: 10.1071/CH99175

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摘要: The heptadentate ligand 2,2',22'-tr is(salicylideneimino)triethylamine (H3trensal) has been complexed with the lanthanides SmIII, EuIII, TbIII and ErIII. resulting [Ln(trensal)] complexes are isomorphous. We demonstrate that method of preparation these is important in ensuring structural homogeneity across LnIII series.

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