Clickable Mesoporous Silica via Functionalization with 1,ω-Alkenes

作者: Sebastiaan A. van den Berg , Jing Tu , Karen M. Sliedregt , Alexander Kros , Tom Wennekes

DOI: 10.1002/ADMI.201300061

关键词:

摘要: Tuning the surface properties of mesoporous silica is desirable for many applications, such as catalysis. We present a new modification method calcined silica, based on thermal grafting 1,7-octadiene. This easy generates high loading terminal alkenes. show that modified directly available thiol-ene click chemistry, which enables wide variety molecules to be attached this alkene-functionalized silica.

参考文章(63)
Jessica M. Rosenholm, Teresa Czuryszkiewicz, Freddy Kleitz, Jarl B. Rosenholm, Mika Lindén, On the nature of the Brønsted acidic groups on native and functionalized mesoporous siliceous SBA-15 as studied by benzylamine adsorption from solution. Langmuir. ,vol. 23, pp. 4315- 4323 ,(2007) , 10.1021/LA062450W
Trevor K. Mischki, Robert L. Donkers, Brian J. Eves, Gregory P. Lopinski, Danial D. M. Wayner, Reaction of alkenes with hydrogen-terminated and photooxidized silicon surfaces. A comparison of thermal and photochemical processes. Langmuir. ,vol. 22, pp. 8359- 8365 ,(2006) , 10.1021/LA060797T
Sarah L. Hruby, Brent H. Shanks, Acid–base cooperativity in condensation reactions with functionalized mesoporous silica catalysts Journal of Catalysis. ,vol. 263, pp. 181- 188 ,(2009) , 10.1016/J.JCAT.2009.02.011
Claudia Haensch, Tina Erdmenger, Martin W. M. Fijten, Stephanie Hoeppener, Ulrich S. Schubert, Fast surface modification by microwave assisted click reactions on silicon substrates. Langmuir. ,vol. 25, pp. 8019- 8024 ,(2009) , 10.1021/LA901140F
J.J Cras, C.A Rowe-Taitt, D.A Nivens, F.S Ligler, Comparison of chemical cleaning methods of glass in preparation for silanization Biosensors and Bioelectronics. ,vol. 14, pp. 683- 688 ,(1999) , 10.1016/S0956-5663(99)00043-3
Frank Hoffmann, Maximilian Cornelius, Jürgen Morell, Michael Fröba, Mesoporöse organisch-anorganische Hybridmaterialien auf Silicabasis Angewandte Chemie. ,vol. 118, pp. 3290- 3328 ,(2006) , 10.1002/ANGE.200503075
Igor Slowing, Brian G. Trewyn, Victor S.-Y. Lin, Effect of surface functionalization of MCM-41-type mesoporous silica nanoparticles on the endocytosis by human cancer cells. Journal of the American Chemical Society. ,vol. 128, pp. 14792- 14793 ,(2006) , 10.1021/JA0645943
Piotr M. Słomkiewicz, Isomerization of linear alkenes on Amberlyst 15 Applied Catalysis A-general. ,vol. 301, pp. 232- 240 ,(2006) , 10.1016/J.APCATA.2005.12.012
Stephan Angloher, Johann Kecht, Thomas Bein, Metal−Organic Modification of Periodic Mesoporous Silica:  Multiply Bonded Systems Chemistry of Materials. ,vol. 19, pp. 5797- 5802 ,(2007) , 10.1021/CM0613556
Chellappah Pathmamanoharan, Albert P. Philipse, Preparation of Small Alkane-Grafted Silica Particles (for Saxs and Sans Studies) from Aqueous Commercial Sols Journal of Colloid and Interface Science. ,vol. 165, pp. 519- 521 ,(1994) , 10.1006/JCIS.1994.1257