Nanocompression of secondary particles of silica aerogel

作者: William Gonçalves , Jonathan Amodeo , Julien Morthomas , Patrice Chantrenne , Michel Perez

DOI: 10.1016/J.SCRIPTAMAT.2018.07.039

关键词:

摘要: Abstract The compression of highly porous silica nanospheres is investigated using molecular dynamics simulations and modeling. ligaments network (3–6 nm) nano-sized sustains the load nanoparticles deform plastically due to localized shear events, at junctions between ligaments. Dangling are more numerous as size nanosphere decreases, thus impacting mechanical response. Based on simulation results, we propose a scaling law that describes particle effect indentation force when applied aerogel secondary under compression.

参考文章(22)
Lorna J. Gibson, Michael F. Ashby, Cellular Solids: Structure and Properties ,(1988)
I. Issa, J. Amodeo, J. Réthoré, L. Joly-Pottuz, C. Esnouf, J. Morthomas, M. Perez, J. Chevalier, K. Masenelli-Varlot, In situ investigation of MgO nanocube deformation at room temperature Acta Materialia. ,vol. 86, pp. 295- 304 ,(2015) , 10.1016/J.ACTAMAT.2014.12.001
Weifu Sun, Qinghua Zeng, Aibing Yu, Kevin Kendall, Calculation of normal contact forces between silica nanospheres. Langmuir. ,vol. 29, pp. 7825- 7837 ,(2013) , 10.1021/LA401087J
T. Woignier, J. Reynes, A. Hafidi Alaoui, I. Beurroies, J. Phalippou, Different kinds of structure in aerogels: relationships with the mechanical properties Journal of Non-crystalline Solids. ,vol. 241, pp. 45- 52 ,(1998) , 10.1016/S0022-3093(98)00747-9
Hajime Tamon, Tsuneyuki Sone, Morio Okazaki, Control of Mesoporous Structure of Silica Aerogel Prepared from TMOS joint international conference on information sciences. ,vol. 188, pp. 162- 167 ,(1997) , 10.1006/JCIS.1996.4731
Ok-Joo Lee, Kun-Hong Lee, Tae Jin Yim, Sun Young Kim, Ki-Pung Yoo, Determination of mesopore size of aerogels from thermal conductivity measurements Journal of Non-crystalline Solids. ,vol. 298, pp. 287- 292 ,(2002) , 10.1016/S0022-3093(01)01041-9
John S. Rivas Murillo, Martina E. Bachlechner, Fritz A. Campo, Ever J. Barbero, Structure and mechanical properties of silica aerogels and xerogels modeled by molecular dynamics simulation Journal of Non-crystalline Solids. ,vol. 356, pp. 1325- 1331 ,(2010) , 10.1016/J.JNONCRYSOL.2010.03.019
John Kieffer, C.Austen Angell, Generation of fractal structures by negative pressure rupturing of SiO2 glass Journal of Non-crystalline Solids. ,vol. 106, pp. 336- 342 ,(1988) , 10.1016/0022-3093(88)90286-4
B.V Derjaguin, V.M Muller, Yu.P Toporov, Effect of contact deformations on the adhesion of particles Journal of Colloid and Interface Science. ,vol. 53, pp. 314- 326 ,(1975) , 10.1016/0021-9797(75)90018-1
B. Storåkers, N.A . Fleck, R.M. McMeeking, The viscoplastic compaction of composite powders Journal of the Mechanics and Physics of Solids. ,vol. 47, pp. 785- 815 ,(1999) , 10.1016/S0022-5096(98)00076-3