Optimization of sample injection in TS-FF-AAS for determination of trace elements
作者： G. Carrone , E. Morzan , R. Candal , M. Tudino
DOI: 10.1016/J.MICROC.2020.105608
关键词:
摘要: Abstract In this work we present a proof of concept for the optimization analytical performance in ThermoSpray Flame Furnace Atomic Absorption Spectrometry (TS-FFAAS) by using different systems sample injection. The influence operational variables was studied with emphasis on characteristics ceramic capillary employed introduction. classic single hole compared to capillaries number inner holes (one, four and six) spatial distribution. signal double simultaneous injection applied zones atomization furnace also evaluated. Determination elements temperature (Ag, Cd Se) done, results shown an figures merit respect TS-FF-AAS conventional assembly increased element volatility. Applications Multi Injection (MI-TS-FF-AAS) evaluated determination “yerba mate” samples; comparison obtained proposed technique other validated ones showed good agreement, reduction amount achieved multi-injection alternative. A discussion focused importance efficient introduction attainable TS-FFAAS applications is provided.
sci-hub.st 参考文章(22)
Fabiana Aparecida Lobo, Adriana Paiva de Oliveira, Mercedes de Moraes, Ana Cristina Villafranca, Comparison of metallic and ceramic tubes as atomization cells for tin determination by TS-FF-AAS Atomic Spectroscopy. ,vol. 28, pp. 17- 23 ,(2007)
James A. Holcombe, Daniel L. G. Borges, Graphite Furnace Atomic Absorption Spectrometry Encyclopedia of Analytical Chemistry. pp. 1- 20 ,(2006) , 10.1002/9780470027318.A5108.PUB2
Edenir Rodrigues Pereira-Filho, Harald Berndt, Marco Aurélio Zezzi Arruda, Simultaneous sample digestion and determination of Cd, Cu and Pb in biological samples using thermospray flame furnace atomic absorption spectrometry (TS-FF-AAS) with slurry sample introduction Journal of Analytical Atomic Spectrometry. ,vol. 17, pp. 1308- 1315 ,(2002) , 10.1039/B202828J
A. Walsh, The application of atomic absorption spectra to chemical analysis Spectrochimica Acta Part A: Molecular Spectroscopy. ,vol. 45, pp. 221- 230 ,(1989) , 10.1016/S0584-8539(89)80272-7
G. A. Petrucelli, P. K. Stocco, M. I. M. S. Bueno, E. R. Pereira-Filho, Tube atomizers in thermospray flame furnace atomic absorption spectrometry: characterization using X-ray fluorescence, scanning electron microscopy and chemometrics Journal of Analytical Atomic Spectrometry. ,vol. 21, pp. 1298- 1304 ,(2006) , 10.1039/B607255K
George L Donati, Clésia C Nascentes, Ana Rita A Nogueira, Marco AZ Arruda, Joaquim A Nóbrega, None, Acid extraction and cloud point preconcentration as sample preparation strategies for cobalt determination in biological materials by thermospray flame furnace atomic absorption spectrometry Microchemical Journal. ,vol. 82, pp. 189- 195 ,(2006) , 10.1016/J.MICROC.2006.01.006
V Muzgin, Electrothermal atomic-absorption and atomic-fluorescence spectrometry with a tungsten-coil atomizer. Talanta. ,vol. 34, pp. 197- 200 ,(1987) , 10.1016/0039-9140(87)80026-7
Clésia C Nascentes, Marco AZ Arruda, Ana Rita A Nogueira, Joaquim A Nóbrega, None, Direct determination of Cu and Zn in fruit juices and bovine milk by thermospray flame furnace atomic absorption spectrometry Talanta. ,vol. 64, pp. 912- 917 ,(2004) , 10.1016/J.TALANTA.2004.04.004
Ezequiel Morzan, Ornela Piano, Jorge Stripeikis, Mabel Tudino, Evaluation of quartz tubes as atomization cells for gold determination by thermospray flame furnace atomic absorption spectrometry Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 77, pp. 58- 62 ,(2012) , 10.1016/J.SAB.2012.07.008
Joanne Davies, Harald Berndt, Improvements in thermospray flame furnace atomic absorption spectrometry Analytica Chimica Acta. ,vol. 479, pp. 215- 223 ,(2003) , 10.1016/S0003-2670(02)01543-X