Hydrogen Peroxide Oxidation of Mono- and Disubstituted Alkylarenes Catalyzed by Dinuclear CoIII-CuII Macrocyclic Complex

作者: H. Golchoubian , A. Ghaziani

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摘要: C-H oxidation of anthracene and eight other alkylarenes with binuclear macrocyclic complex Co I -Cu as a catalyst in the presence 30% aqueous hydrogen peroxide to corresponding carbonyl compounds were studied. The took place selectively at benzylic bond no was observed aromatic ring. reaction is simple, clean high yielding generates water only by-product.