Modeling of supramolecular ordering in molecular liquids: Structure, physicochemical properties and macroscopic manifestations

摘要: Abstract The results of recent developments on modelling supramolecular ordering and macroscopic properties molecular liquids mixtures are reviewed. main attention is paid to the approach based a generalized quasichemical association model for set thermodynamic, dielectric optical mixtures, selforganized by specific bonding. hierarchy theoretical models aggregates considered. nonideal mixture aggregates, polyvariant as regards structure composition, discussed. Interrelations between dielectric, liquid systems, characteristics processes presented. Some problems thermodynamic description internal in have been outlined. Applications functions mixing, permittivity, coefficients isotropic anisotropic Rayleigh light scattering Aggregation liquids, including long range correlations, discussed terms integral differential parameters aggregation. Macroscopic manifestations physicochemical For first time unified reflecting different parameters, this method molecular-structural level has realised.