Modular Flow-Through Platform for Spectroelectrochemical Analysis.
作者： Tomer Noyhouzer , Michael E. Snowden , Ushula M. Tefashe , Janine Mauzeroll
DOI: 10.1021/ACS.ANALCHEM.6B04649
关键词:
摘要: A new type of flow platform for electrochemical and spectroelectrochemical measurements is presented. Finite element method simulations confirm that the hydrodynamic profile within device not turbulent provides an analytical investigation homogeneous kinetics, radical lifetimes, reaction mechanisms. The modular “plug play” configuration allows one to carry out electrochemistry spectroscopy individually or simultaneously. Specific demonstrations electroanalytical using system includes voltammetric analysis organometallic compounds quantitative ascorbic acid in commercial orange juice samples. Combined include luminescence ruthenium ligand exchange reactions iron complexes UV–vis spectroscopy.
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