Kirkwood-Buff integrals of aqueous alcohol binary mixtures

摘要: The Kirkwood-Buff integrals of some binary aqueous alcohol mixtures are computed from the available vapor pressure measurements and compared with previous results as well small angle neutron scattering experiments. emphasis present report is on accuracy that can be achieved by these two different types measurements. This seems to needed, mainly in view discrepancies between various published results, shown herein. It argued agreement peak positions more important than magnitude. In general, very good obtained both methods, sources disagreements discussed. issue computer simulations systems problematics related correlations, microheterogeneity, consequently equally discussed