The transition state in the reduction of ketone by lithium tri-t-butoxyaluminohydride. A kinetic isotope effect study.

作者: Donald C. Wigfield , Frederick W. Gowland

DOI: 10.1016/S0040-4039(01)93677-9

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摘要: Abstract Analysis of experimental and calculated kinetic isotope effects in the title reaction (LiAl(OBu t ) 3 H LiAl(OBu D) leads to conclusion that transition state occurs close mid-point coordinate.

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